با سلام و احترام
امیدوارم حالتون تو این اوضاع خوب باشه
سوالی که دارم مربوط به جلسه اول فصل چهارم این اموزش هستش
شما استانداردی رو برام معرفی کردید تو ویدیو که گفتید
“سیالی در خانواده ترش بودن قرار میگیرد که فشار جزئی هیدروژن سولفید
در آن کمتر از 0.00035 باشد”
این جمله رو بر اساس یک استاندارد گفتید که من متوجه نشدم با اینکه چند بارم هی دوباره نگاه کردم
اگر امکانش هست این استاندارد رو برام بفرستید و اسمشم بگید
بررسی اینکه یک سیال ترش باشد یا SOUR SERVICE بر اساس استانداردهای NACE-MR-0175 & ISO-15156-2 صورت میگیرد در ذیل بخش های مرتبط با سیال ترس و تاثیرات ان را بطور خلاصه برایتان ارسال میکنم :
The NACE MR0175 / ISO 15156 standard defines the requirements for materials selection in H₂S-containing (sour) environments to prevent sulfide stress cracking (SSC) and other forms of corrosion. Below are the key criteria and considerations for sour service as per the latest editions of the standards.
1. Definition of a Sour Environment (ISO 15156-2 / NACE MR0175)
A fluid is considered “sour” if it meets any one of the following conditions:
Parameter | Threshold for Sour Service |
---|---|
Partial Pressure of H₂S (P*H₂S) | ≥ 0.05 psi (0.00345 bar, 0.345 kPa) |
Dissolved H₂S in Water | ≥ 50 ppm (mg/L) in aqueous phase |
Gas Phase H₂S Content | ≥ 100 ppm (0.01 mol%) in gas phase |
Notes:
- If pH₂S < 0.05 psi, the environment is generally considered “sweet”, and sour service requirements may not apply.
- Even trace amounts of H₂S (below the threshold) can cause corrosion in certain conditions (e.g., low pH, high chloride, or high temperature).
- NACE MR0175/ISO 15156-2 also considers CO₂, chlorides, temperature, and pH as influencing factors.
2. Key Requirements for Sour Service (Materials Selection)
A. Carbon & Low-Alloy Steels (CLAS)
- Hardness Limit:
- ≤ 22 HRC (Rockwell C) for most applications.
- ≤ 250 HV (Vickers) for weld zones.
- Heat Treatment: Normalizing & tempering required for high-strength steels.
- SSC Testing: Required per NACE TM0177 (Method A, B, or C).
B. Corrosion-Resistant Alloys (CRAs - Stainless Steels, Nickel Alloys, etc.)
- Duplex Stainless Steels (e.g., UNS S31803, S32205):
- Must have PREN ≥ 40 (Pitting Resistance Equivalent Number).
- Ferrite content controlled (30-50%) to avoid SSC.
- Austenitic Stainless Steels (e.g., 316L, 904L):
- Must be tested if used in high H₂S + chloride environments.
- Nickel Alloys (e.g., Inconel 625, Hastelloy C276):
- Generally resistant but require testing in severe conditions.
C. Non-Metallic Materials (Elastomers, Coatings, Composites)
- Must be H₂S-resistant (e.g., FKM, FFKM for seals).
- NORSOK M-710 or ISO 23936 may apply for elastomer qualification.
3. Testing & Qualification for Sour Service
- SSC Testing (NACE TM0177):
- Method A (Tensile Test) – Slow strain rate in H₂S.
- Method B (Bent Beam Test) – Applied stress in H₂S.
- Method C (C-Ring Test) – For small specimens.
- HIC Testing (NACE TM0284): For pipeline steels (resistance to hydrogen-induced cracking).
- SCC Testing (ISO 15156-3): For CRAs in chloride + H₂S environments.
4. Exceptions & Special Cases
- Low-pH Sour Environments: More stringent requirements (e.g., pH < 3.5).
- High-Temperature Sour Service: Above 150°C, H₂S may become less aggressive, but other corrosion mechanisms (e.g., cracking) may apply.
- Sour Gas with CO₂: Mixed corrosion effects (weight loss + SSC risk).
در ضمن میتوانید این استاندارد رو نیز از اینترنت دانلود نمایید
با تشکر